Season 1965-66

Schoolboy International: 30 April 1966 - England 2 West Germany 1 (85,000) - The England team featured Dave Thomas

"The 1966 World Cup was Wembley's and English football's greatest moment and the stadium staged 17 games during the year."

This is the first official scoreless draw at Wembley (they did so in 1942), in this, the 59th match. England fail to score for first time since 1938.

World Cup Group One: 13 July 1966 - France 1 Mexico 1 (69,237)

World Cup Group One: 19 July 1966 - Mexico 0 Uruguay 0 (61,112)

World Cup Third/Fourth Place Play-off: 28 July 1966 - Portugal 2 USSR 1 (87,696)

"All England's home games were at Wembley from 1966-95 and it became an honour for visiting nations to be invited to play on the hallowed turf."

Season 1966-67

"The Football League Cup Final was played at Wembley for the first time in 1967. Though two Third Division sides won it in three years, it did not diminish the status of the competition which acquired European qualification for its winners."
Football League Cup Final: 4 March 1967 - Queen's Park Rangers 3 West Bromwich Albion 2 (97,952).

Schoolboy International: 29 April 1967 - England 0 Scotland 2 (85,000)

Season 1967-68

Schoolboy International: 27 April 1968 - England 1 West Germany 2.

"Manchester United won Wembley's most famous European Cup Final in 1968."
European Cup Final: 29 May 1968 - Benfica 1 Manchester United 4 (92,000)

"Equestrianism returned to the stadium (on 23-28 July) 1968 and '69, with the Royal International Horse Show. The effect of six consecutive nights of horses pounding the turf was blamed for the pitch in subsequent cup finals, although Wembley's groundsman Percy Young also blamed the new roof because it prevented the wind from drying the grass. Nevertheless, by 1971, it was back to pristine condition."
      

Schoolboy International: 19 April 1969 - England 3 Wales 0 (75,000).
"The England v Scotland fixture was moved to the end of the season in 1969, along with the rest of the British Championship."

Season 1969-70

Schoolboy International: 21 March 1970 - England 2 Scotland 0.

"The next addition to the football calendar arrived in 1970. The FA Trophy was introduced to cater for the semi-professional non-league ranks of the English game. Subtle increases to the numbers of games around this time brought a swift end to the re-emergence of the Wembley Lions speedway team, which required modifications to the corners of the pitch each time they raced."
FA Trophy Final: 2 May 1970 - Macclesfield Town 2 Telford United 0 (28,000) - Telford's manager was Ron Flowers
Schoolboy International: 16 May 1970 - England 3 West Germany 0 (55,000).
 

Season 1970-71

The East German's goal was the 100th goal that England have conceded at Wembley.

Schoolboy International: 6 March 1971 - England 1 Northern Ireland 0 (24,000).
Olympic Qualifying First Leg: 24 March 1971 - Great Britain 1 Bulgaria 0 (3,000).
Schoolboy International: 3 April 1971 - England 5 Netherlands 1 (55,000).

European Cup Final: 2 June 1971 - Ajax Amsterdamsche 2 Panathinaikos 0 (83,000).

Season 1971-72

This Wembley loss ended a run of 19 matches unbeaten at the stadium. Also, the first European Championship match to lose at Wembley.

Schoolboy International: 20 May 1972 - England 4 West Germany 0 (67,000) - a young Ray Wilkins started for England.

Season 1972-73

"On Saturday 5th August 1972, a new chapter in Wembley's history began. The London Rock 'n' Roll Show opened with the Houseshakers, followed by Billy Fury, the first solo performer. British acts, Gary Glitter and Screaming Lord Sutch appeared, but topping the bill were Bill Haley and his Comets, Little Richard and Chuck Berry, who closed the show."

EEC Celebration Match: 3 January 1973 - The Three 2 The Six 0 (36,500) - The Three, players from the United Kingdom, Republic of Ireland and Denmark, were captained by Bobby Charlton, who was making his fiftieth & final appearance at Wembley. It was a match to celebrate the entry of the three countries into the EEC, which already had six member countries, Belgium, France, Netherlands, Italy, Luxembourg and West Germany, The Six.

World Cup preliminary match

The first World Cup match at Wembley since the 1966 World Cup Final.

Schoolboy International: 7 April 1973 - England 3 Netherlands 1 (52,000).

Schoolboy International: 9 June 1973 - England 2 Scotland 4 (32,500). - First schoolboy international to be broadcast live on television.

Season 1973-74

World Cup preliminary match

European Amateur Championship: 31 October 1973 - England 1 West Germany 0 (3,200). - First schoolboy international to be broadcast live on television.

Schoolboy International: 6 April 1974 - England 1 West Germany 0 (3,200). - First schoolboy international to be broadcast live on television.

Schoolboy International: 1 June 1974 - England 4 West Germany 0 (40,000).
"[1974] brought two more competitions to the stadium: the short-lived National Association of Youth Clubs Cup Final, live TV coverage failed to prevent its demise after two years, and... "
NAYC Cup Final: 9 June 1974 - Devonport Dockyard Apprentice Association (Plymouth) 3 Christ Church Youth Club (Sheffield) 1 (10,000) - The first Wembley Cup Final to be played on a Sunday.
"(On 29 June) 1974, (the first) stock-car meeting [was] held."