Since the National Stadium opened its gates to the England senior team on 1 June 2007, there have been, so far, 164 different England players to grace the hallowed turf. 57 of which have made ten or more appearances.
Each player in this list has a National Stadium Number, to reflect their legacy under the arch.
Each column, with the exception of the overall appearances, reflects the players' time at the National Stadium.

38 appearances (1)
NS No.	Player		Born	Club(s)	Pos	Start/ Sub	App	Gls GA	overall & %	Stadium Career
68		Kyle Walker	28 May 1990	Tottenham Hotspur, Manchester City	RB/D	34 4	38	0	93 41%	2011-24	13 years 5 days

37 appearances (2)
NS No.	Player		Born	Club(s)	Pos	Start/ Sub	App	Gls GA	overall & %	Stadium Career
49		Joe Hart	19 April 1987	Manchester City, Torino, West Ham United	GK	36 1	37	16ᵍᵃ	75 49%	2010-17	7 years 174 days
29		Wayne Rooney	24 October 1985	Manchester United, DC United	F	35 2	37	19	120 31%	2007-18	11 years 34 days

30 - 36 appearances (10)
No.	Player		Born Died	Club(s)	Pos	Start/ Sub	App	Gls	overall & %	Stadium Career
58		Jordan Henderson	17 June 1990	Sunderland, Liverpool, Al Ettifaq	A/DM	22 14	36	1	81 44%	2010-23	13 years
84		John Stones	28 May 1994	Everton, Manchester City	CD	33 3	36	1	83 43%	2014-24	10 years 133 days
88		Harry Kane	28 July 1993	Tottenham Hotspur, Bayern München	F	30 6	36	28	103 35%	2015-24	9 years 235 days
82		Raheem Sterling	8 December 1994	Liverpool, Manchester City, Chelsea	M/F	30 4	34	11	82 41%	2014-22	8 years 205 days
4		Steven Gerrard	30 May 1980	Liverpool	M	31 0	31	7	114 27%	2007-14	6 years 363 days
46		James Milner	4 January 1986	Aston Villa, Manchester City, Liverpool	M	15 16	31	0	61 51%	2009-16	6 years 271 days
56		Gary Cahill	19 December 1985	Bolton Wanderers, Chelsea	CD	29 1	30	4	61 49%	2010-18	7 years 272 days

20 - 29 appearances (21)
No.	Player		Born	Club(s)	Pos	Start/ Sub	App	Gls	overall & %	Stadium Career
101		Jordan Pickford	7 March 1994	Everton	GK	28 0	28	16ᵍᵃ	73 38%	2017-24	7 years 7 days
8		Frank Lampard	20 June 1978	West Ham United, Chelsea	M	22 4	26	12	106 25%	2007-13	6 years 313 days
21		Gareth Barry	23 February 1981	Aston Villa, Manchester City	D/M	21 3	24	0	53 45%	2007-12	4 years 191 days
23		Ashley Cole	20 December 1980	Chelsea	LB	24 0	24	0	107 22%	2007-14	6 years 178 days
96		Marcus Rashford	31 October 1997	Manchester United	F	11 13	24	5	60 40%	2016-24	7 years 170 days
118		Declan Rice	14 January 1999	West Ham United, Arsenal	DM	21 3	24	1	62 39%	2019-24	5 years 205 days
40		Theo Walcott	16 March 1989	Arsenal	M/F	17 5	22	2	47 47%	2008-16	8 years 35 days
103		Harry Maguire	5 March 1993	Leicester City, Manchester United	CD	21 1	22	3	63 35%	2017-24	6 years 137 days
38		Glen Johnson	23 August 1984	Portsmouth, Liverpool	RB	20 1	21	1	54 39%	2008-14	6 years 2 days
43		Phil Jagielka	17 August 1982	Everton	CD	16 5	21	2	40 53%	2009-16	7 years 228 days
64		Danny Welbeck	26 November 1990	Sunderland, Manchester United, Arsenal	F	12 8	20	10	42 48%	2011-18	7 years 163 days

10 - 19 appearances (57)
No.	Player		Born Died	Club(s)	Pos	Start/ Sub	App	Gls GA	overall & %	Stadium Career
90		Eric Dier	15 January 1994	Tottenham Hotspur	M/CD	16 3	19	2	49 39%	2015-22	6 years 313 days
135		Phil Foden	28 May 2000	Manchester City	M/F	14 5	19	2	43 44%	2020-24	3 years 333 days
6		John Terry	7 December 1980	Chelsea	CD	18 0	18	3	78 23%	2007-12	5 years 1 day
48		Leighton Baines	11 December 1984	Everton	LB	14 4	18	0	30 60%	2010-15	5 years 24 days
102		Kieran Trippier	19 September 1990	Tottenham Hotspur, Club Atlético de Madrid, Newcastle United	RB/ RWB	15 3	18	0	54 33%	2017-24	6 years 210 days
71		Alex Oxlade-Chamberlain	15 August 1993	Arsenal, Liverpool	M	11 6	17	2	35 49%	2012-19	7 years 165 days
120		Mason Mount	10 January 1999	Chelsea	M/F	13 4	17	3	36 47%	2019-22	3 years 19 days
128		Jack Grealish	10 September 1995	Aston Villa, Manchester City	AM/F	8 9	17	0	38 45%	2020-24	3 years 338 days
34		Jermain Defoe	7 October 1982	Tottenham Hotspur, Portsmouth, Tottenham Hotspur, Sunderland	CF	6 10	16	8	57 28%	2007-17	9 years 125 days
55		Jack Wilshere	1 January 1992	Arsenal	M	9 6	15	0	34 44%	2010-16	5 years 296 days
80		Adam Lallana	10 May 1988	Southampton, Liverpool	M	10 5	15	2	34 44%	2015-18	4 years 132 days
123		Bukayo Saka	5 September 2001	Arsenal	D/M/F	10 5	15	2	43 35%	2020-24	4 years 2 days
136		Jude Bellingham	29 June 2003	Borussia Dortmund, Real Madrid	M	9 6	15	2	40 38%	2020-24	4 years 5 days
16		Peter Crouch	30 January 1981	Liverpool, Portsmouth, Tottenham Hotspur	CF	6 8	14	9	42 33%	2007-10	3 years 169 days
19		Rio Ferdinand	7 November 1978	Manchester United	CD	14 0	14	2	81 17%	2007-11	3 years 317 days
125		Kalvin Phillips	2 December 1995	Leeds United	DM	12 2	14	0	31 45%	2020-23	3 years 9 days
65		Chris Smalling	22 November 1989	Manchester United	RB/ CD	10 3	13	1	31 42%	2011-16	5 years 270 days
69		Daniel Sturridge	1 September 1989	Chelsea, Liverpool	F	9 4	13	5	26 50%	2011-16	4 years 362 days
37		Ashley Young	9 July 1985	Aston Villa, Manchester United	AM/ LWB	7 6	13	3	39 33%	2008-18	10 years 116 days
95		Jesse Lingard	15 December 1992	Manchester United, West Ham United	M	8 5	13	4	31 42%	2016-21	4 years 332 days
22		Shaun Wright-Phillips	25 October 1981	Chelsea, Manchester City	AM	6 6	12	5	36 33%	2007-10	3 years 51 days
91		Dele Alli	11 April 1996	Tottenham Hotspur	M	9 3	12	2	37 32%	2015-19	3 years 164 days
83		Luke Shaw	12 July 1995	Manchester United	LB/ LWB	10 2	12	3	34 35%	2014-22	8 year 205 days
7		David Beckham	2 May 1975	Real Madrid, LA Galaxy, Milan	M	5 6	11	0	115 9%	2007-09	2 years 135 days
17		Michael Carrick	28 July 1981	Manchester United	M	6 5	11	0	34 32%	2007-15	7 years 299 days
66		Phil Jones	21 February 1992	Manchester United	D/M	7 4	11	0	27 41%	2011-17	5 years 363 days
77		Ross Barkley	5 December 1993	Everton, Chelsea	M	5 6	11	0	33 33%	2013-19	6 years 1 day
93		Danny Rose	2 July 1990	Tottenham Hotspur	LB/ WB	6 5	11	0	29 38%	2016-19	3 years 162 days
114		Jadon Sancho	25 March 2000	Borussia Dortmund	RM/F	4 7	11	1	22 50%	2018-21	2 years 238 days
130		Tyrone Mings	13 March 1993	Aston Villa	CD	6 5	11	1	18 61%	2020-22	1 year 4 days
13		Stewart Downing	22 July 1984	Middlesbrough, Aston Villa, Liverpool	LW	3 7	10	0	35 29%	2007-12	4 years 273 days
30		Joleon Lescott	16 August 1982	Everton, Manchester City	CD	6 4	10	0	26 38%	2007-12	4 years 334 days
89		Jamie Vardy	11 January 1987	Leicester City	F	6 4	10	4	26 38%	2015-18	2 years 169 days
129		Reece James	8 December 1999	Chelsea	RB/ RWB	7 3	10	0	15 67%	2020-22	1 year 353 days
112		Ben Chilwell	21 December 1996	Leicester City, Chelsea	LB	10 0	10	0	21 48%	2018-24	5 years 132 days
111		Trent Alexander-Arnold	7 October 1998	Liverpool	FB/M/ RWB	8 2	10	0	33 30%	2018-24	5 years 330 days

A handful of players have played at both the old Wembley Stadium and the new National Stadium, nonemoreso than Steven Gerrard, who followed up his single appearance at the old Stadium in May 2000, with 31 appearances at the new Stadium. His 32nd appearance being almost fourteen years later, to the day. David Beckham, had seventeen at the old Stadium, and eleven at the new. Then Gareth Barry, who made two substitute appearances at the old Stadium, before making 24 at the rebuilt Stadium.
This list is in chronological order, the first to appear at the new Stadium, rather than number of appearances.
Each column, with the exception of the overall appearance, reflects the players' time at both Stadiums.

Ten players
NS. No.	Player		Born	Club(s)	Pos	Start/ Sub	App	Gls	overall & %	Stadium Career
4		Steven Gerrard	30 May 1980	Liverpool	M	32 0	32	7	114 28%	2000-14	13 years 364 days
7		David Beckham	2 May 1975	Manchester United, Real Madrid, LA Galaxy, Milan	M	22 6	28	0	115 24%	1996-2009	13 years 5 days
10		Michael Owen	14 December 1979	Liverpool, Newcastle United	F	11 2	13	5	89 15%	1998-2007	9 years 244 days
12		Kieron Dyer	29 December 1978	Newcastle United, West Ham United	M	2 4	6	0	33 18%	1999-2007	7 years 352 days
19		Rio Ferdinand	7 November 1978	West Ham United FC, Manchester United	CD	15 4	19	2	81 23%	1997-2011	13 years 202 days
20		David James	1 August 1970	Liverpool, Portsmouth	GK	7 1	8	5ᵍᵃ	53 15%	1997-2010	12 years 3 days
21		Gareth Barry	23 February 1981	Aston Villa, Manchester City	D/M	21 5	26	0	53 49%	2000-12	11 years 274 days
24		Emile Heskey	11 January 1978	Leicester City, Liverpool,  Birmingham City, Wigan Athletic, Aston Villa	M/F	7 3	10	1	62 16%	1999-2009	9 years 297 days
25		Phil Neville	21 January 1977	Manchester United, Everton	D/M	7 8	15	0	59 25%	1997-2007	10 years 33 days
28		Sol Campbell	18 September 1974	Tottenham Hotspur, Arsenal, Portsmouth	CD	16 2	18	0	73 22%	1996-2007	11 years 187 days